International Journal of Materials Chemistry and Physics
Articles Information
International Journal of Materials Chemistry and Physics, Vol.1, No.2, Oct. 2015, Pub. Date: Aug. 24, 2015
Investigation on the Deactivation of Residue Fluid Catalytic Cracking (FCC) Catalyst
Pages: 146-155 Views: 3787 Downloads: 2324
[01] M. A. Mustafa, Department of Chemical Engineering, University of Khartoum, Khartoum, Sudan.
[02] Mert Atilhan, Department of Chemical Engineering, Qatar University, Doha, Qatar.
Changes in structure of samples of fresh and spent catalyst are studied for a commercial residue fluid catalytic cracking unit. Quantitative estimates of micropore volume, surface area and pore size distribution are obtained based on Barrett-Joyner-Halenda (BJH), Brunauer-Emmett-Teller (BET), Dollimore-Heal (D-H), Density Functional Theory (DFT), Freundlich, Temkin, t-plot and Langmuir methods. In addition to the insight provided, of the molecular scale crystalline pores, the complementation of SEM-EDS has revealed structural and surface information on the morphology of the particles. A clear degradation of FCC catalyst is evident with a significant reduction in pore volume and surface area. The cause of deactivation is clearly due to fouling, poisoning, dealumination and possibly sintering.
Fluid Catalytic Cracking, Deactivation, Catalyst, Characterization
[01] N. Ravichander, T. Chiranjeevi, D. Gokak, R. Voolapalli, N. Choudary, FCC catalyst and additive evaluation—A case study. Catalysis Today, 2009, 141, 115-119.
[02] D. Rawlence, K. Gosling, FCC catalyst performance evaluation, Applied Catalysis, 1988, 2, 213–237.
[03] H. Cerqueira, G. Caeiro, L. Costa, F. RamôaRibeiro, F. 2008. Deactivation of FCC catalysts, Journal of Molecular Catalysis A: Chemical, 2008, 292, 1-13.
[04] R. Sadeghbeigi, Fluid Catalytic Cracking Handbook: Design, Operation and Troubleshooting of FCC Facilities, Gulf Publishing Company, Houston, TX, USA, 2000.
[05] J. Scherzer, Octane-Enhancing Zeolitic FCC Catalyst: Scinetific and Technical . Marcel Dekker, New York, 1990.
[06] M. Falco, E. Morgado, N. Amadeo, U. Sedran, Accessibility in alumina matrices of FCC catalysts, Applied Catalysis A: General, 2006, 315, 29-34.
[07] Q. Yan-ping, C. Sheng-li, D. Peng, X. Ke-qi, S. Bao-jian, Novel macroporous residua FCC catalysts, Journal of Fuel Chemistry and Technology, 2006, 34, 6, 685-690.
[08] D. Sun, X. Li, M. Brungs, D. Trimm, Encapsulation of heavy metals on spent fluid catalytic cracking catalyst, Water Science and Technology, 1998, 38, 4–5, 211-217.
[09] T. G. Petti, D. Tomczak, C. J. Pereira, W. Cheng, Investigation of nickel species on commercial FCC equilibrium catalysts-implications on catalyst performance and laboratory evaluation, Applied Catalysis A: General, 1998, 169, 1, 95-109.
[10] L. Wu, F. Khalil, G. M. Smith, B. Yilmaz, Jr. R. McGuire, Effect of solvent on the impregnation of contaminant nickel for laboratory deactivation of FCC catalysts, Microporous and Mesoporous Materials, 2015, 207, 195-199.
[11] G. Busca, P. Riani, G. Garbarino, G. Ziemacki, L. Gambino, E. Montanari, R. Millini, The state of nickel in spent Fluid Catalytic Cracking catalysts, Applied Catalysis A: General, 2014, 486, 176-186.
[12] M. Bendiksen, E. Tangstad, T. Myrstad, A comparison of laboratory deactivation methods for FCC catalysts, Applied Catalysis A: General, 1995, 129, 1, 21-31.
[13] M. Torrealba, M. Goldwasser, G. Perot, M. Guisnet, Influence of vanadium on the physicochemical and catalytic properties of USHY zeolite and FCC catalysts, Applied Catalysis A: General, 1992, 90, 1, 35-49.
[14] S. Yang, Y. Chen, C. Li, Metal-resistant FCC catalysts: effect of matrix, Applied Catalysis A: General, 1994, 115, 1, 59-68.
[15] E. Tangstad, M. Bendiksen, T. Myrstad, Effect of sodium deposition of FCC catalysts deactivation, Applied Catalysis A: General, 1997, 150, 1, 85-99.
[16] E. Tangstad, E. Myhrvold, T. Myrstad, A study on the effect of sodium chloride deposition on an FCC catalyst in a cyclic deactivation unit. Applied Catalysis A: General, 2000, 193, 1–2, 113-122.
[17] US, 7456123 B2, (2008) W. Wachter.
[18] D. Wallenstein, B. Kanz, A. Haas, Influence of coke deactivation and vanadium and nickel contamination on the performance of low ZSM-5 levels in FCC catalysts, Applied Catalysis A: General, 2000, 192, 1, 105-123.
[19] BabitaBehera, S.S. Ray, Structural changes of FCC catalyst from fresh to regeneration stages and associated coke in a FCC refining unit: A multinuclear solid state NMR approach, Catalysis Today, 2009, 141, 1–2, 195-204.
[20] S. Haitao, D. Zhijian, Z. Yuxia, Tian Huiping, Effect of coke deposition on the remaining activity of FCC catalysts during gas oil and residue cracking, Catalysis Communications, 2011, 16, 1, 70-74.
[21] F. Pinto, A. Escobar, B. de Oliveira, Y. Lam, H. Cerqueira, B. Louis, J. Tessonnier, D. Su, M. Pereira, The effect of alumina on FCC catalyst in the presence of nickel and vanadium, Applied Catalysis A: General, 2010, 388, 1–2, 15-21.
[22] G. Tonetto, J. Atias, H de Lasa, FCC catalysts with different zeolite crystallite sizes: acidity, structural properties and reactivity, Applied Catalysis A: General, 2004, 270, 1–2, 9-25.
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