International Journal of Materials Chemistry and Physics
Articles Information
International Journal of Materials Chemistry and Physics, Vol.2, No.2, Apr. 2016, Pub. Date: Jan. 18, 2016
Corrosion-Protecting Properties of Bis Quaternized Derivates of Some N-Arylnicotinamides
Pages: 45-49 Views: 2117 Downloads: 1070
Authors
[01] D. A. Pisanenko, Chemical Technologies of Organic Substances, National Engineering University of Ukraine “Kiev Polytechnic Institute”, Kiev, Ukraine.
[02] Yu. E. Klimko, Chemical Technologies of Organic Substances, National Engineering University of Ukraine “Kiev Polytechnic Institute”, Kiev, Ukraine.
[03] A. V. Gaidai, Chemical Technologies of Organic Substances, National Engineering University of Ukraine “Kiev Polytechnic Institute”, Kiev, Ukraine.
Abstract
Some N-Arylnicotinamides were obtained by acylation of 2- and 4-aminopyridines, 3-aminoquinoline with nicotinic acid chloride and converted in bis quaternary salts by quaternization with benzyl chloride, allyl chloride and allyl bromide. Corrosion properties of the salts obtained were studied with respect to corrosion of 08 kp steel in 3M HCl at 40-80°C. Quantum chemical calculations using DFT at the B3LYP/6-31G(d) level have been applied in order to explain the different inhibition efficiencies of these compounds act as inhibitors for iron steel in acid media. The theoretical results were found to be consistent with the experimental data reported.
Keywords
N-Arylnicotinamides, Bis Quaternary Salts on the Base of N-Arylnicotinamides, Synthesis, Hydrochloric Acid, 08kp Steel, Anticorrosion Activity
References
[01] V. S. Sastri. Corrosion Inhibitors. Principles and Applications. Wiley, Chichester; New York, 1998.
[02] Yu. I. Kuznetsov. Organic Inhibitors of Corrosion of Metals. New York: Plenum, 1996.
[03] O. L. Riggs, Jr. Corrosion Inhibitors, NACA, Houston, Texas. 1973, Chap. 2, p. 7-27.
[04] A. G. Gad Allah, H. M. Tamous.// J. Appl. Electrochem. 1990, 20, p. 488.
[05] S. M. Reshetnikov. Inhibitory kislotnoi korrozii metallov (Inhibitors of Acid Corrosion of Metals), Leningrad: Khimiya, 1986.
[06] US Patent 7951754B2. L. Twain, G.R. Meyer, D. Horsup. Publ. 31.5.2011.
[07] S. A. Ali, AMZEL-Sharif // Corr. Eng., Sci. and Technology. 2012, V.47(4), p. 266-271.
[08] M. Saeed, S.A. Ali // Anti-Corr. Methods and Materials. 2003, V.30(6), p. 436-441.
[09] W. Huilang, Z. Fiashen, L. Finy // ibid. 2002. V. 49(2), p. 127-132.
[10] D. A. Pisanenko, Yu. E. Klimko, K.V. Likhnitzkii // Russ. J. Appl. Chem. 2011, V. 84(8), p. 1445-1447.
[11] He Wang, X. Wang, Ha Wang et all // J. Mol. Model. 2007, N13, p. 147-153.
[12] L.H. Madkour, S.K. Elroby // J. Corr. Sci. and Engineering. 2014, V.17, hr.4.
[13] F.B. Growcock.// Corrosion. 1989, 45, p.1003-1007.
[14] A. A. Granovsky. Firefly version 8. http://classic.chem.msk.su/gran/firefly.index.html.
[15] M. W. Schmidt, K. K. Baldridge, J. A. Boatz, et all.// J. Comput. Chem. 1993, 14, p.1347-1363.
[16] R. G. Parr, R. A. Donelly, M. Levy et all .// J. Chem. Phys. 1978, 68, p. 3801-3807.
[17] R. G. Parr, R. G. Pearson // J. Am. Chem.Soc. 1983, 105, p. 7512-7516.
[18] C. O. Badgett, R. C. Provost, C. I. Ogg, et al// J. Am. Chem. Soc. 1945, 67, p. 1153-1158.
[19] O. Clauder, L. Toldy, J. Fabricius // J. Magyar Kem. 1949, 4, p. 596-602.
[20] L. I. Antropov //Zashita metallov.1977, 13, N4, p.387-399.
[21] Y. Karzazi, M. A. Belghiti, A. Dafali, et al // J. Chem. Pharm. Res., 2014, 6(4), p. 689-696.
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