Journal of Nanoscience and Nanoengineering
Articles Information
Journal of Nanoscience and Nanoengineering, Vol.1, No.4, Dec. 2015, Pub. Date: Jan. 9, 2016
Preparation and Characterization of High Content Graphene Nanoplatelet-Polyetherimide Paper
Pages: 252-258 Views: 2497 Downloads: 1777
Authors
[01] Xiaobing Li, Department of Civil Engineering, University of Mississippi, University, USA.
[02] Alharith Manasrah, Department of Civil Engineering, University of Mississippi, University, USA.
[03] Ahmed Al-Ostaz, Department of Civil Engineering, University of Mississippi, University, USA.
[04] Hunain Alkhateb, Department of Civil Engineering, University of Mississippi, University, USA.
[05] Dalton Lincoln, Department of Civil Engineering, University of Mississippi, University, USA.
[06] Grace Rushing, Department of Civil Engineering, University of Mississippi, University, USA.
[07] Alexander H.-D. Cheng, Department of Civil Engineering, University of Mississippi, University, USA.
Abstract
Polyetherimide (PEI)-graphene nanoplatelet (GNP) (PEIGNP) papers, with extremely high GNP loadings (up to nearly 100 wt%), were produced by filtration and hot-press. The impact of the GNP content on the impedance and mechanical properties, such as damping behavior, was investigated. Although the PEIGNP papers showed some decreases in tensile strength and strain at break, dynamic mechanical analysis (DMA) has shown that, compared with either the pristine GNP paper or the neat PEI film, the storage modulus of the PEIGNP papers increased 700% to 2,000% and the capacity to dissipate damping energy in terms of loss modulus was substantially improved by up to 3,000%. The tan δ value gained more than 500%, indicating that a higher fraction of applied energy was converted to heat. In addition, the PEI with relatively smaller molecular weight and the larger GNPs exhibited better damping effects. The results suggest that GNP-reinforced polymer-based nanocomposites could be used in applications that require energy-absorption upon dynamic loading. In addition, all PEIGNP papers in this study exhibited substantially low impedance because of high GNP loadings.
Keywords
Graphene, Mechanical Property, Conductivity, Damping, Polyetherimide
References
[01] Chen, J.H., Jang, C., Xiao, S.D., et al., 2008, “Intrinsic and extrinsic performance limits of graphene devices on SiO2,” Nat. Nanotechnol., 3: 206–209.
[02] Wu H. and Drzal L.T., 2012, “Graphene nanoplatelet paper as a light-weight composite with excellent electrical and thermal conductivity and good gas barrier properties,” Carbon, 50: 1135–1145.
[03] Watanabe, E., Yamaguchi, S., Nakamura, J., et al., 2009, “Ballistic thermal conductance of electrons in graphene ribbons,” Phys. Rev. B, 80: 085404.
[04] Jiang, J.W., Wang, J, S, and Li, B.W, 2009, “Thermal conductance of graphene and dimerite,” Phys. Rev. B, 79: 205418.
[05] Saito, K., Nakamura., J. and Natori, A., 2007, “Ballistic thermal conductance of a graphene sheet,” Phys. Rev. B, 76: 115409.
[06] Balandin, A.A., Ghosh, S., Bao, W.Z., et al., 2008, “Superior thermal conductivity of single-layer graphene,” Nano. Lett., 8: 902–907.
[07] Lee, C., Wei, X., Kysar, J.W., et al., 2008, “Measurement of the elastic properties and intrinsic strength of monolayer graphene,” Science, 321: 385-388.
[08] Wang, C., Li, D., Too, C.O., et al., 2009, “Electrochemical properties of graphene paper electrodes used in lithium batteries,” Chem. Mater., 21: 2604–2606.
[09] Wang, D.-W., Li, F., Zhao, J., et al., 2009, “Fabrication of graphene/polyaniline composite paper via in situ anodic electropolymerization for high-performance flexible electrode,” ACS Nano, 3: 1745–1752.
[10] Liang, J., Wang, Y., Huang, Y., et al., 2009, “Electromagnetic interference shielding of graphene/epoxy composites,” Carbon, 47: 922-925.
[11] Shen, B., Zhai, W. and Zheng, W., 2014, “Ultrathin flexible graphene film: an excellent thermal conducting material with efficient EMI shielding,” Adv. Funct. Mater., 24: 4542–4548.
[12] Lahiri, D., Das, S., Choi, W., et al., 2012, “Unfolding the damping behavior of multilayer graphene membrane in the low-frequency regime,” ACS Nano, 6: 3992–4000.
[13] Valles, C., Nunez, J.D., Benito, A.M., et al., 2012, “Flexible conductive graphene paper obtained by direct and gentle annealing of graphene oxide paper,” Carbon, 50: 835–844.
[14] Zhang, W., He, W. and Jing, X., 2010, “Preparation of a stable graphene dispersion with high concentration by ultrasound,” J. Phys. Chem. B, 114: 10368–10373.
[15] Hu, Y., Li, X., Geng, D., et al., 2013, “Influence of paper thickness on the electrochemical performances of graphene papers as an anode for lithium ion batteries,” Electrochim. Acta, 91: 227– 233.
[16] Xu, L., Wei, N., Xu, X., et al., 2013, “Defect-activated self-assembly of multilayered graphene paper: a mechanically robust architecture with high strength,” J. Mater. Chem. A, 1: 2002-2010.
[17] Li, X., Biswas, S. and Drzal, L.T., 2013, “High temperature vacuum-annealing and hydrogenation modification of exfoliated graphite nanoplatelets”, J. Eng., 2013(2013), Article ID 638576.
[18] Lin, X., Shen, X., Zheng, Q., et al., 2012, “Fabrication of highly-aligned, conductive, and strong graphene papers using ultralarge graphene oxide sheets,” ACS Nano, 6: 10708–10719.
[19] Kim, H.J., Lee, S.-M., Oh, Y.-S., et al., 2014, “Unoxidized graphene/alumina nanocomposite: fracture- and wear-resistance effects of graphene on alumina matrix,” Sci. Rep., 4: 5176.
[20] Fukushima, H. Graphite reinforcements in polymer nanocomposites. East Lansing, MI: Michigan State University, 2003.
[21] Naebe, M., Wang, J., Amini, A., et al., 2014, “Mechanical property and structure of covalent functionalised graphene/epoxy nanocomposites,” Sci. Rep., 4: 1-7.
[22] Li, B., Olson, E., Perugini, A., et al., 2011, “Simultaneous enhancements in damping and static dissipation capability of polyetherimide composites with organosilane surface modified graphene nanoplatelets,” Polymer, 52: 5606–5614.
[23] Grujicic, M., Pandurangan, B., He, T., et al., 2010, “Computational investigation of impact energy absorption capability of polyurea coatings via deformation-induced glass transition,” Mater. Sci. Eng. A, 527: 7741–7751.
[24] Roland, C.M., Fragiadakis, D. and Gamache, R.M., 2010, “Elastomer–steel laminate armor,” Compos. Struct., 92: 1059–1064.
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